Analysis Biogeochemistry

δ13C and δ2H determination on C1 components

Instruments

  • Isotope Ratio Mass Spectrometer DeltaPlus XL (ThermoFisher Scientific)
  • Gas Chromatograph 6890N (Agilent Technologies)

Applications

  • Measurement of δ¹³C and δ²H in CH₄, CO₂, and CH₃I at concentrations ranging from approximately 0.5 – 100 %
DeltaPlus XL isotope mass spectrometer (ThermoFisher Scientific), Gaschromatograph 6890N (Agilent Technologies)

Instruments

  • Enrichment unit (custom-built), coupled with GC 6890N and DeltaPlus XL

Applications

  • Measurement of δ¹³C and δ²H in CH₄ at concentrations ranging from 0.5 – 10,000 ppmv
Enrichment system Delta

Instruments

  • Isotope Ratio Mass Spectrometer Isoprime (Elementar)
  • Gas Chromatograph 6890N (Agilent Technologies)

Applications

  • Measurement of δ¹³C and δ²H in CH₃Cl at concentrations ranging from 0.5 – 10,000 ppmv
Isoprime

Instruments

  • Isotope Ratio Mass Spectrometer Isoprime (Elementar)
  • Gas Chromatograph 6890N (Agilent Technologies)

Applications

  • Measurement of δ¹³C and δ²H in CH₃Cl at concentrations ranging from 0.5 – 10,000 ppmv
MAT 253 isotope mass spectrometer, 6890N gas chromatograph

δ12C and δ18O determination on carbonates

Instruments

  • Isotope Ratio Mass Spectrometer MAT 253 (ThermoFisher Scientific)
  • KIEL IV Carbonate Preparation Device (ThermoFisher Scientific)

Applications

  • Measurement of δ¹³C and δ¹⁸O in carbonates, using very small sample amounts (10 – 100 µg)
MAT 253 isotope mass spectrometer, 6890N gas chromatograph

Mass spectrometric analysis of GC-compatible analytes

Instruments

  • Quadrupole Mass Spectrometer GCMS-QP2020 (Shimadzu)
  • Gas Chromatograph GC-2010 Plus (Shimadzu)

Applications

  • General / Universal applications
Quadrupol-Massenspektrometer GCMS-QP2020 (Shimadzu) Gaschromatograph GC-2010 Plus (Shimadzu)

Instruments

  • Enrichment unit (custom-built), coupled with GC-2010 Plus and GCMS-QP2020

Applications

  • Concentration measurements of CH₃Cl in the pptv range
Enrichment unit (self-built), coupled with GC-2010 Plus and GCMS-QP2020

Instruments

  • Quadrupole Mass Spectrometer 5973 (Hewlett Packard)
  • Gas Chromatograph HP6890 (Hewlett Packard)

Applications

  • General / Universal applications
Quadrupole mass spectrometer 5973 and gas chromatograph HP6890

Instruments

  • Ion Trap Mass Spectrometer 240-MS (Varian)
  • Gas Chromatograph 450-GC (Varian)
  • PAL Autosampler (Varian)

Applications

  • General / Universal applications
Ion trap mass spectrometer 240-MS (Varian), gas chromatograph 450-GC (Varian), and PAL autosampler (Varian)

Analysis of total gas composition

Instruments

  • Gas Chromatograph GC-2010 Plus Tracera (Shimadzu)
  • Barrier Discharge Ionization Detector BID-2010 Plus (Shimadzu)

Applications

  • Total gas composition analysis (H₂, N₂, CO₂, O₂, CH₄, CO) in the concentration range 50 ppm – 100 %
Gas chromatograph GC-2010 Plus Tracera (Shimadzu) Barrier discharge ionization detector (BID-2010 Plus, Shimadzu)

Methane concentration measurements

Instruments

  • Gas Chromatograph GC-14B (Shimadzu)
  • Flame Ionization Detector (FID)

Applications

  • Measurement of CH₄ concentrations in the range 100 ppb – 50 ppm
Gas chromatograph GC-14B (Shimadzu) Flame ionization detector (FID)

Determination of methoxy content

Instruments

  • Gas Chromatograph HP6890 (Hewlett Packard)
  • Flame Ionization Detector (FID)
  • 6890 Series Injector (Agilent)

Applications

  • Determination of methoxy group (-OCH₃) content in organic sample material
Gaschromatograph HP6890 (Hewlett Packard) Flammen-Ionisations-Detektor (FID) 6890 Series Injector (Agilent)

Analysis of volatile organic compounds and alcohols

Instruments

  • Gas Chromatograph GC-2010 Plus (Shimadzu)
  • Flame Ionization Detector (FID)
  • AOC-20i Auto Injector (Shimadzu)

Applications

  • Analysis of volatile organic compounds (VOCs) and alcohols
Gas chromatograph GC-2010 Plus (Shimadzu) Flame ionization detector (FID) AOC-20i Auto injector (Shimadzu)

Analysis of organic C1–C4 compounds

Instruments

  • Gas Chromatograph GC 6000 Vega Series 2 (Carlo Erba)
  • Flame Ionization Detector (FID)

Applications

  • Analysis of C₁ – C₄ components in the concentration range 100 ppb – 1000 ppm
Gas chromatograph GC 6000 Vega Series 2 (Carlo Erba) Flame ionization detector (FID)

Continuous analysis of concentrations and δ13C isotopy of CH4 and CO2 in the atmosphere and water

Instrument

  • Picarro G2201-i

Applications

  • Continuous analysis of concentrations and δ¹³C isotopic composition of CH₄ and CO₂ in the atmosphere and water

Concentration ranges

  • Atmosphere: CH₄: 1.8 – 500 ppm, CO₂: 380 – 2000 ppm
  • Water: CH₄: from 3.6 nmol/L
Picarro G2201-i

Acid digestion of solids

Instrument

  • Digi Prep, Graphite Heating Block (SCP Science)

Applications

  • Preparation of acid digestions
Digi Prep, graphite heating block (SCP Science)

Instrument

  • MLS ETHOS plus, Microwave Digestion System (MLS GmbH)

Applications

  • Preparation of acid digestions
MLS ETHOS plus, microwave digestion system (MLS GmbH)

Instrument

  • MLS ultraCLAVE, Microwave Digestion System (MLS GmbH)

Applications

  • Preparation of acid digestions
MLS ultraCLAVE, microwave digestion system(MLS GmbH)

Ion determination in solutions

Instruments

  • ICS 1100, Ion Chromatograph (Dionex)
  • ASM 3 Autosampler (Dionex)

Applications

  • Quantitative determination of anions in solutions
ICS 1100, ion chromatograph (Dionex)  Autosampler ASM 3 (Dionex)

Instrument

  • Specord 50, UV/VIS Spectrometer (Analytik Jena)

Applications

  • Quantitative determination of cations and anions in solutions
Specord 50, UV/VIS spectrometer (analytik jena)

Determination of carbon in solutions and solids

Instruments

  • TOC-VCPH (Shimadzu)
  • ASI-V Autosampler (Shimadzu)

Applications

  • Quantitative determination of TC, IC, and TOC in solutions
TOC-VCPH (Shimadzu)

Instruments

  • TOC-VCPH (Shimadzu) with Solid Sample Module SSM-5000 A (Shimadzu)

Applications

  • Quantitative determination of TC, IC, and TOC in solid samples
TOC-VCPH (Shimadzu) + Solid State Module SSM-5000 A (Shimadzu)

Elemental analysis in solutions

Instruments

  • Agilent 720 ICP-OES (Agilent Technologies)
  • SC4 DX Autosampler (Elemental Scientific)

Applications

  • Quantitative determination of elements in solutions (major and trace elements)
  • Hydride generation module for the determination of arsenic species As(III) and As(V)
Agilent 720 ICP-OES (Agilent Technologies)  Autosampler SC4 DX (Elemental Scientific)

Element and isotope analyses in solutions

Instruments

  • iCAP TQe ICP-MS (Thermo Scientific)
  • SC2 DX Autosampler (Elemental Scientific)

Applications

  • Quantitative determination of elements and isotopes in solutions (trace and ultra-trace levels)
iCAP TQe ICP-MS (Thermo Scientific) Autosampler SC2 DX (Elemental Scientific)